{"id":17546,"date":"2014-09-28T23:26:31","date_gmt":"2014-09-28T20:26:31","guid":{"rendered":"http:\/\/balarisi.org\/?p=17546"},"modified":"2015-03-30T22:16:15","modified_gmt":"2015-03-30T19:16:15","slug":"bal-orneklerinde-indoxacarb-kalintisinin-ve-bozunma-urunlerinin-tayini-icin-yontem-gelistirilmesi","status":"publish","type":"post","link":"https:\/\/www.beyazkovan.com\/?p=17546","title":{"rendered":"Bal \u00f6rneklerinde indoxacarb kal\u0131nt\u0131s\u0131n\u0131n ve bozunma \u00fcr\u00fcnlerinin tayini i\u00e7in y\u00f6ntem geli\u015ftirilmesi"},"content":{"rendered":"<p><strong>Soner \u00c7ubuk<\/strong><br \/>\nDoktora Tezi, Marmara \u00dcniversitesi \/ Fen Bilimleri Enstit\u00fcs\u00fc \/ Kimya B\u00f6l\u00fcm\u00fc \/ Kimya Anabilim Dal\u0131 \/ Analitik Kimya Bilim Dal\u0131, 2008, 87 s.<br \/>\nTEZ NO: 233347<br \/>\n<!--more--><span style=\"color: #ff6600;\"><a style=\"color: #ff6600;\" href=\"https:\/\/tez.yok.gov.tr\/UlusalTezMerkezi\/tarama.jsp\" target=\"_blank\">Sorgu Penceresine TEZ NO&#8217;yu yazarak Ayr\u0131nt\u0131l\u0131 Bilgi ve PDF d\u00f6k\u00fcmana ula\u015fmak i\u00e7in t\u0131klay\u0131n\u0131z <\/a><\/span><\/p>\n<p><strong>\u00d6ZET<br \/>\n<\/strong>Pestisit kal\u0131nt\u0131s\u0131n\u0131n izlenmesi, yiyecekler i\u00e7indeki pestisitlere insanlar\u0131n maruziyetinin do\u011fru olarak de\u011ferlendirilmesi a\u00e7\u0131s\u0131ndan olduk\u00e7a \u00f6nemlidir. Bu nedenle g\u0131da maddelerinde kal\u0131nt\u0131 d\u00fczeylerinin belirlenmesi ve kullan\u0131lan analitik y\u00f6ntemlerin d\u00fc\u015f\u00fck d\u00fczeyde kal\u0131nt\u0131 \u00f6l\u00e7\u00fcm\u00fc yapabilmesi \u00f6nem kazanmaktad\u0131r. Balda kal\u0131nt\u0131 d\u00fczeyinde bulunan pestisitlerin izin verilen d\u00fczeyde olup olmad\u0131\u011f\u0131n\u0131n belirlenmesi gerekmektedir. Son y\u0131llarda \u00e7e\u015fitli \u00e7al\u0131\u015fmalar yap\u0131lm\u0131\u015f olmas\u0131na kar\u015f\u0131n \u00fclkemizde ballarda pestisit kal\u0131nt\u0131 analizleriyle ilgili s\u0131n\u0131rl\u0131 say\u0131da \u00e7al\u0131\u015fma mevcuttur.\u000b\u00c7al\u0131\u015fmam\u0131zda bal \u00f6rneklerinde Indoxacarb ((S)-metil-7-kloro-2,5-dihidro-2- [(metoksikarbonil) [4-trifluorometoksi) fenil] amino] karbonil] indeno [1,2-e] [1,3,4] oksadiazin- 4a (3H)- karboksilat) kal\u0131nt\u0131s\u0131n\u0131n tayini i\u00e7in analitik metod geli\u015ftirilmi\u015ftir. Indoxacarb i\u00e7eren bal \u00f6rnekleri diklormetan ile ekstrakte edildikten sonra, Indoxacarb&#8217; \u0131n ve ona ait bozunma \u00fcr\u00fcn\u00fcn\u00fcn tayini GC- MS ile yap\u0131lm\u0131\u015ft\u0131r. Geli\u015ftirilen metodun tespit s\u0131n\u0131r\u0131 0.03 mg. kg?1 ve tayin s\u0131n\u0131r\u0131 ise 0.11 mg. kg-1&#8217;dir. Ortalama geri kazan\u0131m % 78.7\u00b15.5 (1.00 mg. kg-1) olarak hesaplanm\u0131\u015ft\u0131r( % 95 g\u00fcven aral\u0131\u011f\u0131, n= 6).\u000bIndoxacarb ile kirlenmi\u015f bal i\u00e7inde be\u015finci ayda tespit edilen bozunma \u00fcr\u00fcn\u00fc 4-(trifluorometoksi) fenilizosiyanat Indoxacarb&#8217; \u0131n literat\u00fcrde belirtilen bozunma \u00fcr\u00fcnlerinden farkl\u0131 bir bozunma \u00fcr\u00fcn\u00fc oarak g\u00f6zlenmi\u015ftir.<strong><br \/>\n<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Soner \u00c7ubuk Doktora Tezi, Marmara \u00dcniversitesi \/ Fen Bilimleri Enstit\u00fcs\u00fc \/ Kimya B\u00f6l\u00fcm\u00fc \/ Kimya Anabilim Dal\u0131 \/ Analitik Kimya Bilim Dal\u0131, 2008, 87 s. TEZ NO: 233347<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_bbp_topic_count":0,"_bbp_reply_count":0,"_bbp_total_topic_count":0,"_bbp_total_reply_count":0,"_bbp_voice_count":0,"_bbp_anonymous_reply_count":0,"_bbp_topic_count_hidden":0,"_bbp_reply_count_hidden":0,"_bbp_forum_subforum_count":0,"footnotes":""},"categories":[36],"tags":[96,231,322],"class_list":["post-17546","post","type-post","status-publish","format-standard","","category-doktora-tezleri","tag-bal-analizi","tag-kalinti-sorunu","tag-soner-cubuk","yazarlar-soner-cubuk","anahtarkelimeler-bal","anahtarkelimeler-bal-analizi","anahtarkelimeler-bal-ve-kalinti-sorunu","anahtarkelimeler-kalinti","anahtarkelimeler-kalinti-analizi","anahtarkelimeler-pestisit-kalintisi"],"_links":{"self":[{"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/posts\/17546","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=17546"}],"version-history":[{"count":1,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/posts\/17546\/revisions"}],"predecessor-version":[{"id":17547,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/posts\/17546\/revisions\/17547"}],"wp:attachment":[{"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=17546"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=17546"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=17546"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}