{"id":17542,"date":"2014-09-28T23:18:05","date_gmt":"2014-09-28T20:18:05","guid":{"rendered":"http:\/\/balarisi.org\/?p=17542"},"modified":"2015-03-30T22:17:28","modified_gmt":"2015-03-30T19:17:28","slug":"bal-orneklerinde-asetamiprid-kalintisinin-ve-bozunma-urununun-tayini-icin-yontem-gelistirilmesi","status":"publish","type":"post","link":"https:\/\/www.beyazkovan.com\/?p=17542","title":{"rendered":"Bal \u00f6rneklerinde asetamiprid kal\u0131nt\u0131s\u0131n\u0131n ve bozunma \u00fcr\u00fcn\u00fcn\u00fcn tayini i\u00e7in y\u00f6ntem geli\u015ftirilmesi"},"content":{"rendered":"<p><strong>Oya Tan\u00e7 Yeter<\/strong><br \/>\nDoktora Tezi, Marmara \u00dcniversitesi \/ Fen Bilimleri Enstit\u00fcs\u00fc \/ Kimya Anabilim Dal\u0131, 2007, 148 s.<br \/>\nTEZ NO: 201587<br \/>\n<!--more--><span style=\"color: #ff6600;\"><a style=\"color: #ff6600;\" href=\"https:\/\/tez.yok.gov.tr\/UlusalTezMerkezi\/tarama.jsp\" target=\"_blank\">Sorgu Penceresine TEZ NO&#8217;yu yazarak Ayr\u0131nt\u0131l\u0131 Bilgi ve PDF d\u00f6k\u00fcmana ula\u015fmak i\u00e7in t\u0131klay\u0131n\u0131z <\/a><\/span><\/p>\n<p><strong>\u00d6ZET<br \/>\n<\/strong>Bal \u00f6rneklerinde asetamiprid ((E)-N1-[(6-kloro-3-piridil)metil-N2-siyano-\u000bN1-metil asetamidin) kal\u0131nt\u0131s\u0131 ve ana bozunma \u00fcr\u00fcn\u00fc IM-1-2 ((E)-N2-karbamoil-N\u0131-\u000b[(6-klloro-3-pridil)metil]-NI-metilasetamidin))&#8217;in tayini i\u00e7in analitik metot\u000bgelistirildi. Asetamiprid i\u00e7eren bal \u00f6rnekleri diklormetan ile ekstrakte edildikten\u000bsonra, asetamipridin ve onun ana bozunma \u00fcr\u00fcn\u00fcn\u00fcn tayini HPLC-DAD ile yap\u0131ld\u0131.\u000bGelistirilen metodun tespit s\u0131n\u0131r\u0131 0.07mgkg?1 ve tayin s\u0131n\u0131r\u0131 ise 0.10mgkg-1&#8217;dir.\u000bOrtalama geri kazan\u0131m oran\u0131 % 96.95\u00b12.59 (1.00 mgkg-1) ve %120\u00b17.05 (0.10\u000bmgkg-1) olarak hesapland\u0131.\u000bAsetamipridin sulu ortamdaki kararl\u0131l\u0131g\u0131 pH:1.30-10.00 aras\u0131ndaki tampon\u000b\u00e7\u00f6zeltilerde incelendi. Tampon \u00e7\u00f6zeltilerdeki asetamiprid ve IM-1-2 miktarlar\u0131ndaki\u000bdegisim 6 ay boyunca HPLC ile izlendi. Ayr\u0131ca \u00f6rneklerdeki degisim GC-MS ile\u000bkalitatif olarak da izlendi. 6 ay sonunda pH:1.30, 2.00, 9.00, 10.00&#8217;da asetamiprid\u000bkademeli olarak bozundu. En y\u00fcksek bozunma oran\u0131 pH:10.00&#8217;da g\u00f6zlendi. Olusan\u000bbozunma \u00fcr\u00fcnleri GC-EI-MS, GC-PCI-MS ve NMR teknikleri ile IM-1-4 (N-metil-\u000b(6-kloro-3-piridil)metilamin) ve IM-1-2 olarak tan\u0131mland\u0131.\u000bAyr\u0131ca asetamipridin degisik t\u00fcrdeki bal ortamlar\u0131ndaki kararl\u0131l\u0131g\u0131 \u00e7al\u0131s\u0131ld\u0131. ATP\u000bile kirletilen bal \u00f6rnekleri 20, 30 ve 40oC&#8217;de tutularak, asetamiprid ve IM-1-2\u000bmiktarlar\u0131ndaki degisim 6 ay boyunca HPLC-DAD ile izlendi. \u00d6rneklerdeki degisim\u000bkalitatif olarak ayr\u0131ca GC-MS ile izlendi. Tampon \u00e7\u00f6zeltilerdeki bozunma\u000b\u00fcr\u00fcnlerinin balda da meydana geldigi, bozunma \u00fcr\u00fcnlerinin ve bozunma h\u0131zlar\u0131n\u0131n\u000bbal t\u00fcr\u00fcne bagl\u0131 olmad\u0131g\u0131 g\u00f6zlendi.<strong><br \/>\n<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Oya Tan\u00e7 Yeter Doktora Tezi, Marmara \u00dcniversitesi \/ Fen Bilimleri Enstit\u00fcs\u00fc \/ Kimya Anabilim Dal\u0131, 2007, 148 s. TEZ NO: 201587<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_bbp_topic_count":0,"_bbp_reply_count":0,"_bbp_total_topic_count":0,"_bbp_total_reply_count":0,"_bbp_voice_count":0,"_bbp_anonymous_reply_count":0,"_bbp_topic_count_hidden":0,"_bbp_reply_count_hidden":0,"_bbp_forum_subforum_count":0,"footnotes":""},"categories":[36],"tags":[96,558,320],"class_list":["post-17542","post","type-post","status-publish","format-standard","","category-doktora-tezleri","tag-bal-analizi","tag-kalinti-analizi","tag-oya-tanc-yeter","yazarlar-oya-tanc-yeter","anahtarkelimeler-bal","anahtarkelimeler-bal-analizi","anahtarkelimeler-bal-ve-kalinti-sorunu","anahtarkelimeler-kalinti","anahtarkelimeler-kalinti-analizi","anahtarkelimeler-pestisit-kalintisi"],"_links":{"self":[{"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/posts\/17542","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=17542"}],"version-history":[{"count":1,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/posts\/17542\/revisions"}],"predecessor-version":[{"id":17543,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=\/wp\/v2\/posts\/17542\/revisions\/17543"}],"wp:attachment":[{"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=17542"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=17542"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.beyazkovan.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=17542"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}